Features of Electrical Properties of Composite Material of the CaSO4-H3PO4-C System
DOI:
https://doi.org/10.52575/2687-0959-2025-57-4-290-297Keywords:
Calcium Sulfate, Solid Electrolyte, Impedance Spectroscopy Method, Ionic ConductivityAbstract
This paper presents the results of a study of the electrical properties of a microstructurally heterogeneous composite material consisting of a calcium sulfate, phosphoric acid, and carbon system. The electrical conductivity and conductivity mechanism of the material samples at room temperature were studied. The material’s electrical conductivity was found to be quite high and typical of solid electrolytes.
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Kosir J., Mousavihashemi S., Suominen M., Kobets A., Wilson B.P., Rautama E.-L., Kallio T. Supervalent doping and its effect on the thermal, structural and electrochemical properties of Li7La3Zr2O12 solid electrolytes. Advanced Materials. 2024;5:5260–5274.
Ali A.A.A., Acharya S., Bhongale K., Shirbhate S., Kulkarni S., Joshi S. Investigation of Sr doping effect on oxygen ion de-localization in Gd2Ti2O7 pyrochlore system and its influence on charge relaxation dynamics and ionic conductivity: as electrolyte for IT-SOFCs. Ionics. 2024;30:7293–7310.
Gupta M., Shirbhate S., Ojha P., Acharya S. Processing and conductivity behavior of La, Sm, Fe singly and doubly doped ceria: As electrolytes for IT-SOFCs. Solid State Ionics. 2018;320:199–209.
Nguyen M.H., Park S. Synergetic effect of Li-ion concentration and triple doping on ionic conductivity of Li7La3Zr2O12 solid electrolyte. Nanomaterials. 2022;12:2946.
Yang T., Li Y., Wu W., Cao Z., He W., Gao Y., Liu J., Li G. The synergistic effect of dual substitution of Al and Sb on structure and ionic conductivity of Li7La3Zr2O12 ceramic. Ceramics International. 2018;44:1538.
Dashjav E., Ma Q., Xu Q., Tsai C.-L., Giarola M., Mariotto G., Tietz F. The influence of water on the electrical conductivity of aluminum-substituted lithium titanium phosphates. Solid State Ionics. 2018;321:83–90.
Ivanov O.N., Trusova Ya.V. Electrical conductivity peculiarities of SrTiO3-ZrO2 ceramic system. Ceramics International. 2016;42:5245–5249.
Abe Y., Nishizaki S., Muroi T., Kato Y., Hench L.L. Conversion of gypsum into a superprotonic conductor. Materials Research Innovations. 2006;10:93–109.
Nikulin I., Nikulicheva T., Vyazmin V., Ivanov O., Anosov N., Telpova O. Effect of high-temperature treatment with orthophosphoric acid on the phase composition, elemental composition, microstructure and electrical properties of calcium sulfate hemihydrate. Journal of Solid State Chemistry. 2026;353:125656.
Simic M., Jeoti V., Stojanovic G.M. Parameter extraction of the Cole-impedance model for in-situ monitoring of electrochemical sources. Journal of Energy Storage. 2024;77:109895.
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